Mononuclear complexes and a coordination polymer of the 2-pyridylamino ((NHPy)-Py-2) functionalized P(V) ligand

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Mononuclear complexes and a coordination polymer of the 2-pyridylamino ((NHPy)-Py-2) functionalized P(V) ligand. / Pal, Souvik; Jana, Partha; Nayek, Hari Pada.

I: RSC Advances, Vol. 4, Nr. 51, 2014, s. 26902-26906.

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Pal, Souvik ; Jana, Partha ; Nayek, Hari Pada. / Mononuclear complexes and a coordination polymer of the 2-pyridylamino ((NHPy)-Py-2) functionalized P(V) ligand. I: RSC Advances. 2014 ; Vol. 4, Nr. 51. s. 26902-26906.

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TY - JOUR

T1 - Mononuclear complexes and a coordination polymer of the 2-pyridylamino ((NHPy)-Py-2) functionalized P(V) ligand

AU - Pal, Souvik

AU - Jana, Partha

AU - Nayek, Hari Pada

PY - 2014

Y1 - 2014

N2 - Three mononuclear metal complexes, [{PO2((NHPy)-Py-2)(2)}(2)M] [Py-2 - 2-pyridyl; M - Zn (1), Ni (2), Co (3)], have been synthesized by reacting metal nitrates with tetrakis(2-pyridylamino)phosphonium chloride, [P((NHPy)-Py-2)(4)]Cl, under solvothermal reaction conditions. The ligand, [P((NHPy)-Py-2)(4)]Cl, is hydrolyzed in the reaction medium. All of the complexes are isostructural and show an octahedral geometry around the metal ion. A coordination polymer, [{P((NHPy)-Py-2)(4)Cu2Cl4}ClO4](infinity) (4), was also obtained by treating [P((NHPy)-Py-2)(4)]Cl with copper perchlorate hexahydrate at ambient temperature. All of the complexes were characterized by standard analytical techniques. The solid-state structures of 1-4 were established by single crystal X-ray diffraction analysis. The optical properties of 1-4 have been investigated.

AB - Three mononuclear metal complexes, [{PO2((NHPy)-Py-2)(2)}(2)M] [Py-2 - 2-pyridyl; M - Zn (1), Ni (2), Co (3)], have been synthesized by reacting metal nitrates with tetrakis(2-pyridylamino)phosphonium chloride, [P((NHPy)-Py-2)(4)]Cl, under solvothermal reaction conditions. The ligand, [P((NHPy)-Py-2)(4)]Cl, is hydrolyzed in the reaction medium. All of the complexes are isostructural and show an octahedral geometry around the metal ion. A coordination polymer, [{P((NHPy)-Py-2)(4)Cu2Cl4}ClO4](infinity) (4), was also obtained by treating [P((NHPy)-Py-2)(4)]Cl with copper perchlorate hexahydrate at ambient temperature. All of the complexes were characterized by standard analytical techniques. The solid-state structures of 1-4 were established by single crystal X-ray diffraction analysis. The optical properties of 1-4 have been investigated.

U2 - 10.1039/c4ra02258k

DO - 10.1039/c4ra02258k

M3 - Article

VL - 4

SP - 26902

EP - 26906

JO - RSC Advances

T2 - RSC Advances

JF - RSC Advances

SN - 2046-2069

IS - 51

ER -