Ru-Catalyzed Completely Deoxygenative Coupling of 2-Arylethanols through Base-Induced Net Decarbonylation

Forskningsoutput: TidskriftsbidragArtikel i vetenskaplig tidskrift

Abstract

Substituted arylethanols can be coupled by using a readily available Ru catalyst in a fully deoxygenative manner to produce hydrocarbon chains in one step. Control experiments indicate that the first deoxygenation occurs through an aldol condensation, whereas the second occurs through a base-induced net decarbonylation. This double deoxygenation enables further development in the use of alcohols as versatile and green alkylating reagents, as well as in other fields, such as deoxygenation and upgrading of overfunctionalized biomass to produce hydrocarbons.

Detaljer

Författare
Enheter & grupper
Externa organisationer
  • Lund University
Forskningsområden

Ämnesklassifikation (UKÄ) – OBLIGATORISK

  • Biokatalys och enzymteknik

Nyckelord

Originalspråkengelska
Sidor (från-till)803-807
Antal sidor5
TidskriftChemistry - A European Journal
Volym24
Utgåva nummer4
StatusPublished - 2018 jan 19
PublikationskategoriForskning
Peer review utfördJa