A monocarboxylate-bridged diiron(III) mu-oxido complex that catalyzes alkane oxidation by hydrogen peroxide

Martin Jarenmark; Elena A. Turitsyna; Matti Haukka; Albert A. Shteinman; Ebbe Nordlander

doi:10.1039/c0nj00293c

A monocarboxylate-bridged diiron(III) mu-oxido complex that catalyzes alkane oxidation by hydrogen peroxide

Martin Jarenmark, Elena A. Turitsyna, Matti Haukka, Albert A. Shteinman, Ebbe Nordlander

Kemisk fysik

Forskningsoutput: Tidskriftsbidrag › Artikel i vetenskaplig tidskrift › Peer review

Sammanfattning

Reaction of the ligand 2-(N-isopropyl-N-{(2-pyridyl)methyl}aminomethyl)- 6-(N-(carboxymethyl)-N-((2-pyridyl)-methyl) aminomethyl)- 4-methylphenol (H2IPCPMP) with two equivalents of Fe(ClO4)(2) and two equivalents of sodium pivalate in air leads to the formation of the mu-oxido, mu-carboxylato-bridged diiron complex [{Fe(H-IPCPMP)}(2)(mu-O)(Piv)]ClO4 (1) (Piv = pivalate). Complex 1 is capable of catalysing the oxidation of cyclohexane or 1,2-cis-dimethylcyclohexane by hydrogen peroxide, leading to the formation of the corresponding cyclohexanone and cyclohexanol, as well as a small amount of cyclohexyl hydroperoxide.

Originalspråk	engelska
Sidor (från-till)	2118-2121
Tidskrift	New Journal of Chemistry
Volym	34
Nummer	10
DOI	https://doi.org/10.1039/c0nj00293c
Status	Published - 2010

Bibliografisk information

The information about affiliations in this record was updated in December 2015.
The record was previously connected to the following departments: Chemical Physics (S) (011001060)

Ämnesklassifikation (UKÄ)

Atom- och molekylfysik och optik

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10.1039/c0nj00293c

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title = "A monocarboxylate-bridged diiron(III) mu-oxido complex that catalyzes alkane oxidation by hydrogen peroxide",

abstract = "Reaction of the ligand 2-(N-isopropyl-N-{(2-pyridyl)methyl}aminomethyl)- 6-(N-(carboxymethyl)-N-((2-pyridyl)-methyl) aminomethyl)- 4-methylphenol (H2IPCPMP) with two equivalents of Fe(ClO4)(2) and two equivalents of sodium pivalate in air leads to the formation of the mu-oxido, mu-carboxylato-bridged diiron complex [{Fe(H-IPCPMP)}(2)(mu-O)(Piv)]ClO4 (1) (Piv = pivalate). Complex 1 is capable of catalysing the oxidation of cyclohexane or 1,2-cis-dimethylcyclohexane by hydrogen peroxide, leading to the formation of the corresponding cyclohexanone and cyclohexanol, as well as a small amount of cyclohexyl hydroperoxide.",

author = "Martin Jarenmark and Turitsyna, {Elena A.} and Matti Haukka and Shteinman, {Albert A.} and Ebbe Nordlander",

note = "The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)",

year = "2010",

doi = "10.1039/c0nj00293c",

language = "English",

volume = "34",

pages = "2118--2121",

journal = "New Journal of Chemistry",

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publisher = "Royal Society of Chemistry",

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T1 - A monocarboxylate-bridged diiron(III) mu-oxido complex that catalyzes alkane oxidation by hydrogen peroxide

AU - Jarenmark, Martin

AU - Turitsyna, Elena A.

AU - Haukka, Matti

AU - Shteinman, Albert A.

AU - Nordlander, Ebbe

N1 - The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)

PY - 2010

Y1 - 2010

N2 - Reaction of the ligand 2-(N-isopropyl-N-{(2-pyridyl)methyl}aminomethyl)- 6-(N-(carboxymethyl)-N-((2-pyridyl)-methyl) aminomethyl)- 4-methylphenol (H2IPCPMP) with two equivalents of Fe(ClO4)(2) and two equivalents of sodium pivalate in air leads to the formation of the mu-oxido, mu-carboxylato-bridged diiron complex [{Fe(H-IPCPMP)}(2)(mu-O)(Piv)]ClO4 (1) (Piv = pivalate). Complex 1 is capable of catalysing the oxidation of cyclohexane or 1,2-cis-dimethylcyclohexane by hydrogen peroxide, leading to the formation of the corresponding cyclohexanone and cyclohexanol, as well as a small amount of cyclohexyl hydroperoxide.

AB - Reaction of the ligand 2-(N-isopropyl-N-{(2-pyridyl)methyl}aminomethyl)- 6-(N-(carboxymethyl)-N-((2-pyridyl)-methyl) aminomethyl)- 4-methylphenol (H2IPCPMP) with two equivalents of Fe(ClO4)(2) and two equivalents of sodium pivalate in air leads to the formation of the mu-oxido, mu-carboxylato-bridged diiron complex [{Fe(H-IPCPMP)}(2)(mu-O)(Piv)]ClO4 (1) (Piv = pivalate). Complex 1 is capable of catalysing the oxidation of cyclohexane or 1,2-cis-dimethylcyclohexane by hydrogen peroxide, leading to the formation of the corresponding cyclohexanone and cyclohexanol, as well as a small amount of cyclohexyl hydroperoxide.

U2 - 10.1039/c0nj00293c

DO - 10.1039/c0nj00293c

M3 - Article

SN - 1369-9261

VL - 34

SP - 2118

EP - 2121

JO - New Journal of Chemistry

JF - New Journal of Chemistry

IS - 10

ER -

A monocarboxylate-bridged diiron(III) mu-oxido complex that catalyzes alkane oxidation by hydrogen peroxide

Sammanfattning

Bibliografisk information

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