Bis(mu(3)-iodo)-pentakis(mu(2)-iodo)-penta-copper(I) - A fully ordered, isolated [Cu5I7](2-) cluster

Ehsan Jalilian; Sven Lidin

doi:10.1016/j.solidstatesciences.2010.03.019

Bis(mu(3)-iodo)-pentakis(mu(2)-iodo)-penta-copper(I) - A fully ordered, isolated [Cu5I7](2-) cluster

Ehsan Jalilian, Sven Lidin

Centrum för analys och syntes

Forskningsoutput: Tidskriftsbidrag › Artikel i vetenskaplig tidskrift › Peer review

Sammanfattning

Two new compounds, [(C4H9)(4)P](2)[Cu5I7], and [(C4H9)(4) P](2)[Cu5I7]center dot CH3COCH2OH were synthesized by solvolysis and their crystal structures were solved. The first compound is disordered, but the solvate represents the first example of a fully ordered [Cu5I7](2-) cluster. It displays a molecular symmetry very close to C-2. Both compounds crystallize in space group P2(1)/c. (C) 2010 Elsevier Masson SAS. All rights reserved.

Originalspråk	engelska
Sidor (från-till)	768-772
Tidskrift	Solid State Sciences
Volym	13
Nummer	4
DOI	https://doi.org/10.1016/j.solidstatesciences.2010.03.019
Status	Published - 2011

Bibliografisk information

The information about affiliations in this record was updated in December 2015.
The record was previously connected to the following departments: Polymer and Materials Chemistry (LTH) (011001041)

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Kemi

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10.1016/j.solidstatesciences.2010.03.019

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title = "Bis(mu(3)-iodo)-pentakis(mu(2)-iodo)-penta-copper(I) - A fully ordered, isolated [Cu5I7](2-) cluster",

abstract = "Two new compounds, [(C4H9)(4)P](2)[Cu5I7], and [(C4H9)(4) P](2)[Cu5I7]center dot CH3COCH2OH were synthesized by solvolysis and their crystal structures were solved. The first compound is disordered, but the solvate represents the first example of a fully ordered [Cu5I7](2-) cluster. It displays a molecular symmetry very close to C-2. Both compounds crystallize in space group P2(1)/c. (C) 2010 Elsevier Masson SAS. All rights reserved.",

keywords = "Copper(I) iodide cluster, Structure",

author = "Ehsan Jalilian and Sven Lidin",

note = "The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Polymer and Materials Chemistry (LTH) (011001041)",

year = "2011",

doi = "10.1016/j.solidstatesciences.2010.03.019",

language = "English",

volume = "13",

pages = "768--772",

journal = "Solid State Sciences",

issn = "1873-3085",

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T1 - Bis(mu(3)-iodo)-pentakis(mu(2)-iodo)-penta-copper(I) - A fully ordered, isolated [Cu5I7](2-) cluster

AU - Jalilian, Ehsan

AU - Lidin, Sven

N1 - The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Polymer and Materials Chemistry (LTH) (011001041)

PY - 2011

Y1 - 2011

N2 - Two new compounds, [(C4H9)(4)P](2)[Cu5I7], and [(C4H9)(4) P](2)[Cu5I7]center dot CH3COCH2OH were synthesized by solvolysis and their crystal structures were solved. The first compound is disordered, but the solvate represents the first example of a fully ordered [Cu5I7](2-) cluster. It displays a molecular symmetry very close to C-2. Both compounds crystallize in space group P2(1)/c. (C) 2010 Elsevier Masson SAS. All rights reserved.

AB - Two new compounds, [(C4H9)(4)P](2)[Cu5I7], and [(C4H9)(4) P](2)[Cu5I7]center dot CH3COCH2OH were synthesized by solvolysis and their crystal structures were solved. The first compound is disordered, but the solvate represents the first example of a fully ordered [Cu5I7](2-) cluster. It displays a molecular symmetry very close to C-2. Both compounds crystallize in space group P2(1)/c. (C) 2010 Elsevier Masson SAS. All rights reserved.

KW - Copper(I) iodide cluster

KW - Structure

U2 - 10.1016/j.solidstatesciences.2010.03.019

DO - 10.1016/j.solidstatesciences.2010.03.019

M3 - Article

SN - 1873-3085

VL - 13

SP - 768

EP - 772

JO - Solid State Sciences

JF - Solid State Sciences

IS - 4

ER -

Bis(mu(3)-iodo)-pentakis(mu(2)-iodo)-penta-copper(I) - A fully ordered, isolated [Cu5I7](2-) cluster

Sammanfattning

Bibliografisk information

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Single crystal and powder diffractometers

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