Csp3−H Activation without Chelation Assistance in an Iridium Pincer Complex Forming Cyclometallated Products

David A. Ahlstrand, Alexey V. Polukeev, Rocío Marcos, Mårten S G Ahlquist, Ola F. Wendt

Forskningsoutput: TidskriftsbidragArtikel i vetenskaplig tidskriftPeer review

Sammanfattning

Cyclometallation of 8-methylquinoline and 2-(dimethylamino)-pyridine in an iridium-based pincer complex is described. The C−H activation of 2-(dimethylamino)pyridine is not chelation assisted, which has not been described before for Csp3−H bonds in cyclometallation reactions. The mechanism of the cyclometallation of 2-(dimethylamino)pyridine was studied by DFT calculations and kinetic measurements.

Originalspråkengelska
Sidor (från-till)1748-1751
Antal sidor4
TidskriftChemistry - A European Journal
Volym23
Nummer8
DOI
StatusPublished - 2017

Ämnesklassifikation (UKÄ)

  • Analytisk kemi

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