Sammanfattning
Cyclometallation of 8-methylquinoline and 2-(dimethylamino)-pyridine in an iridium-based pincer complex is described. The C−H activation of 2-(dimethylamino)pyridine is not chelation assisted, which has not been described before for Csp3−H bonds in cyclometallation reactions. The mechanism of the cyclometallation of 2-(dimethylamino)pyridine was studied by DFT calculations and kinetic measurements.
Originalspråk | engelska |
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Sidor (från-till) | 1748-1751 |
Antal sidor | 4 |
Tidskrift | Chemistry - A European Journal |
Volym | 23 |
Nummer | 8 |
DOI | |
Status | Published - 2017 |
Ämnesklassifikation (UKÄ)
- Analytisk kemi