Sammanfattning
Ambient pressure x-ray photoelectron spectroscopy (APXPS) can provide a compelling platform for studying an analyte's oxidation and reduction reactions in solutions. This paper presents proof-of-principle operando measurements of a model organometallic complex, iron hexacyanide, in an aqueous solution using the dip-and-pull technique. The data demonstrates that the electrochemically active liquid meniscuses on the working electrodes can undergo controlled redox reactions which were observed using APXPS. A detailed discussion of several critical experimental considerations is included as guidance for anyone undertaking comparable experiments.
Originalspråk | engelska |
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Artikelnummer | 244701 |
Tidskrift | Journal of Chemical Physics |
Volym | 157 |
Nummer | 24 |
DOI | |
Status | Published - 2022 dec. 28 |
Ämnesklassifikation (UKÄ)
- Annan kemi
- Den kondenserade materiens fysik (Här ingår: Materialfysik, nanofysik)