Far-Infrared Investigation of the Benzene-Water Complex: The Identification of Large-Amplitude Motion and Tunneling Pathways

J. Andersen, R. Wugt Larsen, J. Ceponkus, P. Uvdal, B. Nelander

Forskningsoutput: TidskriftsbidragArtikel i vetenskaplig tidskriftPeer review

Sammanfattning

The far-infrared spectrum of the weakly OH···πhydrogen-bonded benzene-water complex has been studied in neon and argon matrices, below 30 K. The in-plane water libration has been observed in both neon and argon for H2O and D2O complexed with C6H6 and C6D6 but not for the corresponding complexes involving HDO. Both H2O and D2O can tunnel between the two possible hydrogen bonds. This is not possible for HDO. The reported far-infrared observations have implications for the interpretation of the previously obtained molecular beam microwave spectrum of the benzene-water complex.

Originalspråkengelska
Sidor (från-till)513-519
TidskriftJournal of Physical Chemistry A
Volym124
Nummer3
DOI
StatusPublished - 2020

Ämnesklassifikation (UKÄ)

  • Fysikalisk kemi

Fingeravtryck

Utforska forskningsämnen för ”Far-Infrared Investigation of the Benzene-Water Complex: The Identification of Large-Amplitude Motion and Tunneling Pathways”. Tillsammans bildar de ett unikt fingeravtryck.

Citera det här