Influence of formation path on the CH2BrCl2+ dissociation dynamics

K Le Guen; M Ahmad; Denis Céolin; P Lablanquie; C Miron; F Penent; P Morin; M Simon

doi:10.1063/1.2008256

Influence of formation path on the CH2BrCl2+ dissociation dynamics

K Le Guen, M Ahmad, Denis Céolin, P Lablanquie, C Miron, F Penent, P Morin, M Simon

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Forskningsoutput: Tidskriftsbidrag › Artikel i vetenskaplig tidskrift › Peer review

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To get further insight into the CH2BrCl site-selective fragmentation previously observed upon inner-shell ionization, we have performed high-resolution Br 3d and Cl 2p Auger and spin-orbit resolved Br 3d Auger spectra, and studied the dissociation properties of the CH2BrCl2+ dication formed at threshold by means of threshold electron pair-ion coincidence measurements. The key point is that the origin of site-specific bond breaking is found in the Auger decay itself, as it preferentially populates selected dication states. Whereas the predominance of the C-Br bond breaking is observed in both threshold and inner-shell studies, no signature of selective C-Cl rupture is reported for the dication formed at threshold.

Originalspråk	engelska
Tidskrift	Journal of Chemical Physics
Volym	123
Nummer	8
DOI	https://doi.org/10.1063/1.2008256
Status	Published - 2005

Ämnesklassifikation (UKÄ)

Atom- och molekylfysik och optik

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10.1063/1.2008256

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title = "Influence of formation path on the CH2BrCl2+ dissociation dynamics",

abstract = "To get further insight into the CH2BrCl site-selective fragmentation previously observed upon inner-shell ionization, we have performed high-resolution Br 3d and Cl 2p Auger and spin-orbit resolved Br 3d Auger spectra, and studied the dissociation properties of the CH2BrCl2+ dication formed at threshold by means of threshold electron pair-ion coincidence measurements. The key point is that the origin of site-specific bond breaking is found in the Auger decay itself, as it preferentially populates selected dication states. Whereas the predominance of the C-Br bond breaking is observed in both threshold and inner-shell studies, no signature of selective C-Cl rupture is reported for the dication formed at threshold.",

author = "{Le Guen}, K and M Ahmad and Denis C{\'e}olin and P Lablanquie and C Miron and F Penent and P Morin and M Simon",

year = "2005",

doi = "10.1063/1.2008256",

language = "English",

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journal = "Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics (AIP)",

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TY - JOUR

T1 - Influence of formation path on the CH2BrCl2+ dissociation dynamics

AU - Le Guen, K

AU - Ahmad, M

AU - Céolin, Denis

AU - Lablanquie, P

AU - Miron, C

AU - Penent, F

AU - Morin, P

AU - Simon, M

PY - 2005

Y1 - 2005

N2 - To get further insight into the CH2BrCl site-selective fragmentation previously observed upon inner-shell ionization, we have performed high-resolution Br 3d and Cl 2p Auger and spin-orbit resolved Br 3d Auger spectra, and studied the dissociation properties of the CH2BrCl2+ dication formed at threshold by means of threshold electron pair-ion coincidence measurements. The key point is that the origin of site-specific bond breaking is found in the Auger decay itself, as it preferentially populates selected dication states. Whereas the predominance of the C-Br bond breaking is observed in both threshold and inner-shell studies, no signature of selective C-Cl rupture is reported for the dication formed at threshold.

AB - To get further insight into the CH2BrCl site-selective fragmentation previously observed upon inner-shell ionization, we have performed high-resolution Br 3d and Cl 2p Auger and spin-orbit resolved Br 3d Auger spectra, and studied the dissociation properties of the CH2BrCl2+ dication formed at threshold by means of threshold electron pair-ion coincidence measurements. The key point is that the origin of site-specific bond breaking is found in the Auger decay itself, as it preferentially populates selected dication states. Whereas the predominance of the C-Br bond breaking is observed in both threshold and inner-shell studies, no signature of selective C-Cl rupture is reported for the dication formed at threshold.

U2 - 10.1063/1.2008256

DO - 10.1063/1.2008256

M3 - Article

SN - 0021-9606

VL - 123

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 8

ER -

Influence of formation path on the CH2BrCl2+ dissociation dynamics

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