Luminescent PhotoCORMs: Enabling/Disabling CO Delivery upon Blue Light Irradiation

Vitor C. Weiss; Giliandro Farias; André L. Amorim; Fernando R. Xavier; Tiago P. Camargo; Mayana B. Bregalda; Matti Haukka; Ebbe Nordlander; Bernardo De Souza; Rosely A. Peralta

doi:10.1021/acs.inorgchem.0c00638

Luminescent PhotoCORMs: Enabling/Disabling CO Delivery upon Blue Light Irradiation

Vitor C. Weiss, Giliandro Farias, André L. Amorim, Fernando R. Xavier, Tiago P. Camargo, Mayana B. Bregalda, Matti Haukka, Ebbe Nordlander, Bernardo De Souza, Rosely A. Peralta

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Forskningsoutput: Tidskriftsbidrag › Artikel i vetenskaplig tidskrift › Peer review

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The new luminescent carbonyl compounds [Mn(Oxa-H)(CO)3Br] (1) and [Mn(Oxa-NMe2)(CO)3Br] (2) were synthesized and fully characterized. Complexes 1 and 2 showed CO release under blue light (λ453). Spectroscopic techniques and TD-DFT and SOC-TD-DFT calculations indicated that 1 and 2 release the Oxa-H and Oxa-NMe2 coligands in addition to the carbonyl ligands, increasing the luminescence during photoinduction.

Originalspråk	engelska
Sidor (från-till)	13078-13090
Antal sidor	13
Tidskrift	Inorganic Chemistry
Volym	59
Nummer	18
Tidigt onlinedatum	2020
DOI	https://doi.org/10.1021/acs.inorgchem.0c00638
Status	Published - 2020

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@article{e06282511a044609a25c290e6f0d6bb3,

title = "Luminescent PhotoCORMs: Enabling/Disabling CO Delivery upon Blue Light Irradiation",

abstract = "The new luminescent carbonyl compounds [Mn(Oxa-H)(CO)3Br] (1) and [Mn(Oxa-NMe2)(CO)3Br] (2) were synthesized and fully characterized. Complexes 1 and 2 showed CO release under blue light (λ453). Spectroscopic techniques and TD-DFT and SOC-TD-DFT calculations indicated that 1 and 2 release the Oxa-H and Oxa-NMe2 coligands in addition to the carbonyl ligands, increasing the luminescence during photoinduction.",

author = "Weiss, {Vitor C.} and Giliandro Farias and Amorim, {Andr{\'e} L.} and Xavier, {Fernando R.} and Camargo, {Tiago P.} and Bregalda, {Mayana B.} and Matti Haukka and Ebbe Nordlander and {De Souza}, Bernardo and Peralta, {Rosely A.}",

year = "2020",

doi = "10.1021/acs.inorgchem.0c00638",

language = "English",

volume = "59",

pages = "13078--13090",

journal = "Inorganic Chemistry",

issn = "1520-510X",

publisher = "The American Chemical Society (ACS)",

number = "18",

}

TY - JOUR

T1 - Luminescent PhotoCORMs

T2 - Enabling/Disabling CO Delivery upon Blue Light Irradiation

AU - Weiss, Vitor C.

AU - Farias, Giliandro

AU - Amorim, André L.

AU - Xavier, Fernando R.

AU - Camargo, Tiago P.

AU - Bregalda, Mayana B.

AU - Haukka, Matti

AU - Nordlander, Ebbe

AU - De Souza, Bernardo

AU - Peralta, Rosely A.

PY - 2020

Y1 - 2020

N2 - The new luminescent carbonyl compounds [Mn(Oxa-H)(CO)3Br] (1) and [Mn(Oxa-NMe2)(CO)3Br] (2) were synthesized and fully characterized. Complexes 1 and 2 showed CO release under blue light (λ453). Spectroscopic techniques and TD-DFT and SOC-TD-DFT calculations indicated that 1 and 2 release the Oxa-H and Oxa-NMe2 coligands in addition to the carbonyl ligands, increasing the luminescence during photoinduction.

AB - The new luminescent carbonyl compounds [Mn(Oxa-H)(CO)3Br] (1) and [Mn(Oxa-NMe2)(CO)3Br] (2) were synthesized and fully characterized. Complexes 1 and 2 showed CO release under blue light (λ453). Spectroscopic techniques and TD-DFT and SOC-TD-DFT calculations indicated that 1 and 2 release the Oxa-H and Oxa-NMe2 coligands in addition to the carbonyl ligands, increasing the luminescence during photoinduction.

U2 - 10.1021/acs.inorgchem.0c00638

DO - 10.1021/acs.inorgchem.0c00638

M3 - Article

C2 - 32902965

AN - SCOPUS:85091324313

SN - 1520-510X

VL - 59

SP - 13078

EP - 13090

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 18

ER -

Luminescent PhotoCORMs: Enabling/Disabling CO Delivery upon Blue Light Irradiation

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