On the adsorption and reactivity of element 114, flerovium

A. Yakushev; L. Lens; Ch.E. Düllmann; J. Khuyagbaatar; E. Jäger; J. Krier; J. Runke; H.M. Albers; M. Asai; M. Block; J. Despotopulos; A. Di Nitto; K. Eberhardt; U. Forsberg; P. Golubev; M. Götz; S. Götz; H. Haba; L. Harkness-Brennan; R.-D. Herzberg; F.P. Heßberger; D. Hinde; A. Hübner; D. Judson; B. Kindler; Y. Komori; J. Konki; J.V. Kratz; N. Kurz; M. Laatiaoui; S. Lahiri; B. Lommel; M. Maiti; A.K. Mistry; Ch. Mokry; K.J. Moody; Y. Nagame; J.P. Omtvedt; P. Papadakis; V. Pershina; D. Rudolph; L.G. Sarmiento; T.K. Sato; M. Schädel; P. Scharrer; B. Schausten; D.A. Shaughnessy; J. Steiner; P. Thörle-Pospiech; A. Toyoshima; N. Trautmann; K. Tsukada; J. Uusitalo; K.-O. Voss; A. Ward; M. Wegrzecki; N. Wiehl; E. Williams; V. Yakusheva

doi:10.3389/fchem.2022.976635

On the adsorption and reactivity of element 114, flerovium

A. Yakushev, L. Lens, Ch.E. Düllmann, J. Khuyagbaatar, E. Jäger, J. Krier, J. Runke, H.M. Albers, M. Asai, M. Block, J. Despotopulos, A. Di Nitto, K. Eberhardt, U. Forsberg, P. Golubev, M. Götz, S. Götz, H. Haba, L. Harkness-Brennan, R.-D. HerzbergF.P. Heßberger, D. Hinde, A. Hübner, D. Judson, B. Kindler, Y. Komori, J. Konki, J.V. Kratz, N. Kurz, M. Laatiaoui, S. Lahiri, B. Lommel, M. Maiti, A.K. Mistry, Ch. Mokry, K.J. Moody, Y. Nagame, J.P. Omtvedt, P. Papadakis, V. Pershina, D. Rudolph, L.G. Sarmiento, T.K. Sato, M. Schädel, P. Scharrer, B. Schausten, D.A. Shaughnessy, J. Steiner, P. Thörle-Pospiech, A. Toyoshima, N. Trautmann, K. Tsukada, J. Uusitalo, K.-O. Voss, A. Ward, M. Wegrzecki, N. Wiehl, E. Williams, V. Yakusheva

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Sammanfattning

Flerovium (Fl, element 114) is the heaviest element chemically studied so far. To date, its interaction with gold was investigated in two gas-solid chromatography experiments, which reported two different types of interaction, however, each based on the level of a few registered atoms only. Whereas noble-gas-like properties were suggested from the first experiment, the second one pointed at a volatile-metal-like character. Here, we present further experimental data on adsorption studies of Fl on silicon oxide and gold surfaces, accounting for the inhomogeneous nature of the surface, as it was used in the experiment and analyzed as part of the reported studies. We confirm that Fl is highly volatile and the least reactive member of group 14. Our experimental observations suggest that Fl exhibits lower reactivity towards Au than the volatile metal Hg, but higher reactivity than the noble gas Rn.

Originalspråk	engelska
Artikelnummer	976635
Antal sidor	11
Tidskrift	Frontiers in Chemistry
Volym	10
DOI	https://doi.org/10.3389/fchem.2022.976635
Status	Published - 2022 aug. 25

Ämnesklassifikation (UKÄ)

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10.3389/fchem.2022.976635Licens: CC BY

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Tillhörande pressmeddelandet GSI Darmstadt, Tyskland.

5 Artikel i vetenskaplig tidskrift
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Spectroscopy along flerovium decay chains. II. Fine structure in odd-A ²⁸⁹Fl
Cox, D. M., Såmark-Roth, A., Rudolph, D., Sarmiento, L. G., Clark, R. M., Egido, J. L., Golubev, P., Heery, J., Yakushev, A., Åberg, S., Albers, H. M., Albertsson, M., Block, M., Brand, H., Calverley, T., Cantemir, R., Carlsson, B. G., Düllmann, C. E., Eberth, J., Fahlander, C., & 34 andraForsberg, U., Gates, J. M., Giacoppo, F., Götz, M., Götz, S., Herzberg, R-D., Hrabar, Y., Jäger, E., Judson, D., Khuyagbaatar, J., Kindler, B., Kojouharov, I., Kratz, J. V., Krier, J., Kurz, N., Lens, L., Ljungberg, J., Lommel, B., Louko, J., Meyer, C-C., Mistry, A., Mokry, C., Papadakis, P., Parr, E., Pore, J. L., Ragnarsson, I., Runke, J., Schädel, M., Schaffner, H., Schausten, B., Shaughnessy, D. A., Thörle-Pospiech, P., Trautmann, N. & Uusitalo, J., 2023 feb. 6, I: Physical Review C. 107, 2, 6 s., L021301.
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Spectroscopy along flerovium decay chains. III. Details on experiment, analysis, ²⁸²Cn, and spontaneous fission branches
Såmark-Roth, A., Cox, D. M., Rudolph, D., Sarmiento, L. G., Albertsson, M., Carlsson, B. G., Egido, J. L., Golubev, P., Heery, J., Yakushev, A., Åberg, S., Albers, H. M., Block, M., Brand, H., Calverley, T., Cantemir, R., Clark, R. M., Düllmann, C. E., Eberth, J., Fahlander, C., & 34 andraForsberg, U., Gates, J. M., Giacoppo, F., Götz, M., Götz, S., Herzberg, R-D., Hrabar, Y., Jäger, E., Judson, D., Khuyagbaatar, J., Kindler, B., Kojouharov, I., Kratz, J. V., Krier, J., Kurz, N., Lens, L., Ljungberg, J., Lommel, B., Louko, J., Meyer, C-C., Mistry, A., Mokry, C., Papadakis, P., Parr, E., Pore, J. L., Ragnarsson, I., Runke, J., Schädel, M., Schaffner, H., Schausten, B., Shaughnessy, D. A., Thörle-Pospiech, P., Trautmann, N. & Uusitalo, J., 2023 feb. 6, I: Physical Review C. 107, 2, 12 s., 024301.
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Results and plans for nuclear spectroscopy of superheavy nuclei: the Lund perspective
Rudolph, D., 2022 dec. 12, I: European Physical Journal A. 58, 12, 19 s., 242.
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ChaSE Lundium: Karakterisering av nya supertunga grundämnen
Rudolph, D., Åberg, S., Carlsson, G., Düllmann, C. E., Golubev, P., Sarmiento Pico, L., Forsberg, U., Toivanen, J., Ward, D., Cox, D., Lorenz, C., Såmark-Roth, A., Albertsson, M., Ljungberg, J., Hrabar, Y., Lindholm, Y., Lindqvist, K., Lundberg, M. & Andersson, P.
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Kärnstruktur vid stabilitetsgränsen: Spektroskopi av särskilda isotoper
Rudolph, D., Fahlander, C., Golubev, P., Sarmiento Pico, L., Cox, D., Hrabar, Y., Såmark-Roth, A., Forsberg, U., Lorenz, C., Lalovic, N., Lalovic, N., Forsberg, U., Gellanki, J., Hoischen, R., Johansson, E., Andersson, L., du Rietz, R., Ekman, J. & Andreoiu, C.
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Yakushev, A., Lens, L., Düllmann, C. E., Khuyagbaatar, J., Jäger, E., Krier, J., Runke, J., Albers, H. M., Asai, M., Block, M., Despotopulos, J., Di Nitto, A., Eberhardt, K., Forsberg, U., Golubev, P., Götz, M., Götz, S., Haba, H., Harkness-Brennan, L., ... Yakusheva, V. (2022). On the adsorption and reactivity of element 114, flerovium. Frontiers in Chemistry, 10, Artikel 976635. https://doi.org/10.3389/fchem.2022.976635

@article{65339a589de147ce98f0ae7ab6c51f39,

title = "On the adsorption and reactivity of element 114, flerovium",

abstract = "Flerovium (Fl, element 114) is the heaviest element chemically studied so far. To date, its interaction with gold was investigated in two gas-solid chromatography experiments, which reported two different types of interaction, however, each based on the level of a few registered atoms only. Whereas noble-gas-like properties were suggested from the first experiment, the second one pointed at a volatile-metal-like character. Here, we present further experimental data on adsorption studies of Fl on silicon oxide and gold surfaces, accounting for the inhomogeneous nature of the surface, as it was used in the experiment and analyzed as part of the reported studies. We confirm that Fl is highly volatile and the least reactive member of group 14. Our experimental observations suggest that Fl exhibits lower reactivity towards Au than the volatile metal Hg, but higher reactivity than the noble gas Rn.",

keywords = "nuclear chemistry, radiochemistry, superheavy elements, element 114, adsorption, recoil separators",

author = "A. Yakushev and L. Lens and Ch.E. D{\"u}llmann and J. Khuyagbaatar and E. J{\"a}ger and J. Krier and J. Runke and H.M. Albers and M. Asai and M. Block and J. Despotopulos and {Di Nitto}, A. and K. Eberhardt and U. Forsberg and P. Golubev and M. G{\"o}tz and S. G{\"o}tz and H. Haba and L. Harkness-Brennan and R.-D. Herzberg and F.P. He{\ss}berger and D. Hinde and A. H{\"u}bner and D. Judson and B. Kindler and Y. Komori and J. Konki and J.V. Kratz and N. Kurz and M. Laatiaoui and S. Lahiri and B. Lommel and M. Maiti and A.K. Mistry and Ch. Mokry and K.J. Moody and Y. Nagame and J.P. Omtvedt and P. Papadakis and V. Pershina and D. Rudolph and L.G. Sarmiento and T.K. Sato and M. Sch{\"a}del and P. Scharrer and B. Schausten and D.A. Shaughnessy and J. Steiner and P. Th{\"o}rle-Pospiech and A. Toyoshima and N. Trautmann and K. Tsukada and J. Uusitalo and K.-O. Voss and A. Ward and M. Wegrzecki and N. Wiehl and E. Williams and V. Yakusheva",

year = "2022",

month = aug,

day = "25",

doi = "10.3389/fchem.2022.976635",

language = "English",

volume = "10",

journal = "Frontiers in Chemistry",

issn = "2296-2646",

publisher = "Frontiers Media S. A.",

}

Yakushev, A, Lens, L, Düllmann, CE, Khuyagbaatar, J, Jäger, E, Krier, J, Runke, J, Albers, HM, Asai, M, Block, M, Despotopulos, J, Di Nitto, A, Eberhardt, K, Forsberg, U, Golubev, P, Götz, M, Götz, S, Haba, H, Harkness-Brennan, L, Herzberg, R-D, Heßberger, FP, Hinde, D, Hübner, A, Judson, D, Kindler, B, Komori, Y, Konki, J, Kratz, JV, Kurz, N, Laatiaoui, M, Lahiri, S, Lommel, B, Maiti, M, Mistry, AK, Mokry, C, Moody, KJ, Nagame, Y, Omtvedt, JP, Papadakis, P, Pershina, V, Rudolph, D , Sarmiento, LG, Sato, TK, Schädel, M, Scharrer, P, Schausten, B, Shaughnessy, DA, Steiner, J, Thörle-Pospiech, P, Toyoshima, A, Trautmann, N, Tsukada, K, Uusitalo, J, Voss, K-O, Ward, A, Wegrzecki, M, Wiehl, N, Williams, E & Yakusheva, V 2022, 'On the adsorption and reactivity of element 114, flerovium', Frontiers in Chemistry, vol. 10, 976635. https://doi.org/10.3389/fchem.2022.976635

TY - JOUR

T1 - On the adsorption and reactivity of element 114, flerovium

AU - Yakushev, A.

AU - Lens, L.

AU - Düllmann, Ch.E.

AU - Khuyagbaatar, J.

AU - Jäger, E.

AU - Krier, J.

AU - Runke, J.

AU - Albers, H.M.

AU - Asai, M.

AU - Block, M.

AU - Despotopulos, J.

AU - Di Nitto, A.

AU - Eberhardt, K.

AU - Forsberg, U.

AU - Golubev, P.

AU - Götz, M.

AU - Götz, S.

AU - Haba, H.

AU - Harkness-Brennan, L.

AU - Herzberg, R.-D.

AU - Heßberger, F.P.

AU - Hinde, D.

AU - Hübner, A.

AU - Judson, D.

AU - Kindler, B.

AU - Komori, Y.

AU - Konki, J.

AU - Kratz, J.V.

AU - Kurz, N.

AU - Laatiaoui, M.

AU - Lahiri, S.

AU - Lommel, B.

AU - Maiti, M.

AU - Mistry, A.K.

AU - Mokry, Ch.

AU - Moody, K.J.

AU - Nagame, Y.

AU - Omtvedt, J.P.

AU - Papadakis, P.

AU - Pershina, V.

AU - Rudolph, D.

AU - Sarmiento, L.G.

AU - Sato, T.K.

AU - Schädel, M.

AU - Scharrer, P.

AU - Schausten, B.

AU - Shaughnessy, D.A.

AU - Steiner, J.

AU - Thörle-Pospiech, P.

AU - Toyoshima, A.

AU - Trautmann, N.

AU - Tsukada, K.

AU - Uusitalo, J.

AU - Voss, K.-O.

AU - Ward, A.

AU - Wegrzecki, M.

AU - Wiehl, N.

AU - Williams, E.

AU - Yakusheva, V.

PY - 2022/8/25

Y1 - 2022/8/25

N2 - Flerovium (Fl, element 114) is the heaviest element chemically studied so far. To date, its interaction with gold was investigated in two gas-solid chromatography experiments, which reported two different types of interaction, however, each based on the level of a few registered atoms only. Whereas noble-gas-like properties were suggested from the first experiment, the second one pointed at a volatile-metal-like character. Here, we present further experimental data on adsorption studies of Fl on silicon oxide and gold surfaces, accounting for the inhomogeneous nature of the surface, as it was used in the experiment and analyzed as part of the reported studies. We confirm that Fl is highly volatile and the least reactive member of group 14. Our experimental observations suggest that Fl exhibits lower reactivity towards Au than the volatile metal Hg, but higher reactivity than the noble gas Rn.

AB - Flerovium (Fl, element 114) is the heaviest element chemically studied so far. To date, its interaction with gold was investigated in two gas-solid chromatography experiments, which reported two different types of interaction, however, each based on the level of a few registered atoms only. Whereas noble-gas-like properties were suggested from the first experiment, the second one pointed at a volatile-metal-like character. Here, we present further experimental data on adsorption studies of Fl on silicon oxide and gold surfaces, accounting for the inhomogeneous nature of the surface, as it was used in the experiment and analyzed as part of the reported studies. We confirm that Fl is highly volatile and the least reactive member of group 14. Our experimental observations suggest that Fl exhibits lower reactivity towards Au than the volatile metal Hg, but higher reactivity than the noble gas Rn.

KW - nuclear chemistry

KW - radiochemistry

KW - superheavy elements

KW - element 114

KW - adsorption

KW - recoil separators

UR - https://www.gsi.de/en/start/news/details/2022/09/15/chemie-114

U2 - 10.3389/fchem.2022.976635

DO - 10.3389/fchem.2022.976635

M3 - Article

C2 - 36092655

SN - 2296-2646

VL - 10

JO - Frontiers in Chemistry

JF - Frontiers in Chemistry

M1 - 976635

ER -

On the adsorption and reactivity of element 114, flerovium

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Forskningsoutput

Spectroscopy along flerovium decay chains. II. Fine structure in odd-A 289Fl

Spectroscopy along flerovium decay chains. III. Details on experiment, analysis, 282Cn, and spontaneous fission branches

Results and plans for nuclear spectroscopy of superheavy nuclei: the Lund perspective

Projekt

ChaSE Lundium: Karakterisering av nya supertunga grundämnen

Kärnstruktur vid stabilitetsgränsen: Spektroskopi av särskilda isotoper

Citera det här

Spectroscopy along flerovium decay chains. II. Fine structure in odd-A ²⁸⁹Fl

Spectroscopy along flerovium decay chains. III. Details on experiment, analysis, ²⁸²Cn, and spontaneous fission branches