Optimization of U and Pu traces separation by chromatography for analytical purposes: influence of U/Pu mass ratio

Ch Maillard; G. Pédehontaa-Hiaa; E. Esbelin; C. Rivier; D. Roudil

doi:10.1007/s10967-018-6014-y

Optimization of U and Pu traces separation by chromatography for analytical purposes: influence of U/Pu mass ratio

Ch Maillard, G. Pédehontaa-Hiaa, E. Esbelin, C. Rivier, D. Roudil

French Alternative Energies and Atomic Energy Commission (CEA)

Forskningsoutput: Tidskriftsbidrag › Artikel i vetenskaplig tidskrift › Peer review

Sammanfattning

A study related to the separations of uranium traces in a concentrated Pu solution and plutonium traces in a concentrated U solution was performed (with Pu/U or U/Pu = 10²–10⁵). Its objective was to determine the U–Pu separation performances for a low U and Pu concentration range, namely: Pu solutions of 2.5 mg L⁻¹ to 2.5 g L⁻¹ containing traces of U (25 µg L⁻¹), U solutions of 10 µg L⁻¹ to 10 mg L⁻¹ containing traces of Pu (100 ng L⁻¹). The developed methods proved to be efficient and its robustness was confirmed with the treatment of high-activity real samples.

Originalspråk	engelska
Sidor (från-till)	1253-1261
Antal sidor	9
Tidskrift	Journal of Radioanalytical and Nuclear Chemistry
Volym	317
Nummer	3
DOI	https://doi.org/10.1007/s10967-018-6014-y
Status	Published - 2018 sep. 1
Externt publicerad	Ja

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title = "Optimization of U and Pu traces separation by chromatography for analytical purposes: influence of U/Pu mass ratio",

abstract = "A study related to the separations of uranium traces in a concentrated Pu solution and plutonium traces in a concentrated U solution was performed (with Pu/U or U/Pu = 102–105). Its objective was to determine the U–Pu separation performances for a low U and Pu concentration range, namely: Pu solutions of 2.5 mg L−1 to 2.5 g L−1 containing traces of U (25 µg L−1), U solutions of 10 µg L−1 to 10 mg L−1 containing traces of Pu (100 ng L−1). The developed methods proved to be efficient and its robustness was confirmed with the treatment of high-activity real samples.",

keywords = "Chromatography, Plutonium traces, Pu valency adjustment, Separations, Uranium traces",

author = "Ch Maillard and G. P{\'e}dehontaa-Hiaa and E. Esbelin and C. Rivier and D. Roudil",

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doi = "10.1007/s10967-018-6014-y",

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T1 - Optimization of U and Pu traces separation by chromatography for analytical purposes

T2 - influence of U/Pu mass ratio

AU - Maillard, Ch

AU - Pédehontaa-Hiaa, G.

AU - Esbelin, E.

AU - Rivier, C.

AU - Roudil, D.

PY - 2018/9/1

Y1 - 2018/9/1

N2 - A study related to the separations of uranium traces in a concentrated Pu solution and plutonium traces in a concentrated U solution was performed (with Pu/U or U/Pu = 102–105). Its objective was to determine the U–Pu separation performances for a low U and Pu concentration range, namely: Pu solutions of 2.5 mg L−1 to 2.5 g L−1 containing traces of U (25 µg L−1), U solutions of 10 µg L−1 to 10 mg L−1 containing traces of Pu (100 ng L−1). The developed methods proved to be efficient and its robustness was confirmed with the treatment of high-activity real samples.

AB - A study related to the separations of uranium traces in a concentrated Pu solution and plutonium traces in a concentrated U solution was performed (with Pu/U or U/Pu = 102–105). Its objective was to determine the U–Pu separation performances for a low U and Pu concentration range, namely: Pu solutions of 2.5 mg L−1 to 2.5 g L−1 containing traces of U (25 µg L−1), U solutions of 10 µg L−1 to 10 mg L−1 containing traces of Pu (100 ng L−1). The developed methods proved to be efficient and its robustness was confirmed with the treatment of high-activity real samples.

KW - Chromatography

KW - Plutonium traces

KW - Pu valency adjustment

KW - Separations

KW - Uranium traces

U2 - 10.1007/s10967-018-6014-y

DO - 10.1007/s10967-018-6014-y

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SN - 0236-5731

VL - 317

SP - 1253

EP - 1261

JO - Journal of Radioanalytical and Nuclear Chemistry

JF - Journal of Radioanalytical and Nuclear Chemistry

IS - 3

ER -

Optimization of U and Pu traces separation by chromatography for analytical purposes: influence of U/Pu mass ratio

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