Selective vibrational excitation in the resonant Auger decay following core-to-pi transitions in N2O

O. Travnikova, Denis Céolin, Z. Bao, K. J. Borve, T. Tanaka, M. Hoshino, H. Kato, H. Tanaka, J. R. Harries, Y. Tamenori, G. Pruemper, T. Lischke, X. -J. Liu, M. N. Piancastelli, K. Ueda

Forskningsoutput: Kapitel i bok/rapport/Conference proceedingKonferenspaper i proceedingPeer review

Sammanfattning

In N2O a detailed study of the vibrational distribution of the (X) over tilde state reached after decay of core-to-pi* excitation of N terminal, N central and 0 1s core levels is reported. We observe a change in the relative intensity of bending versus stretching modes while scanning the photon energy across all three resonances. While this effect is known to be due to the Renner-Teller splitting in the core-excited states, we could derive that the antisymmetric stretching is excited mainly in the decay of the N terminal 1s-to-pi* excitation. An explanation for such selectivity is provided in terms of interplay of vibrational structure on potential energy surfaces of different electronic states involved in the process. (C) 2010 Elsevier B.V. All rights reserved.
Originalspråkengelska
Titel på värdpublikationJournal of Electron Spectroscopy and Related Phenomena
FörlagElsevier
Sidor129-134
Volym181
DOI
StatusPublished - 2010
Evenemang11th International Conference on Electronic Spectroscopy and Structure (ICESS - 11) - Nara, Japan
Varaktighet: 2009 okt. 62009 okt. 10

Publikationsserier

Namn
Nummer2-3
Volym181
ISSN (tryckt)0368-2048

Konferens

Konferens11th International Conference on Electronic Spectroscopy and Structure (ICESS - 11)
Land/TerritoriumJapan
OrtNara
Period2009/10/062009/10/10

Ämnesklassifikation (UKÄ)

  • Atom- och molekylfysik och optik (Här ingår: Kemisk fysik, kvantoptik)

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