Structure and Bonding of Ethylene Oxide on Si(100)

Franz Hennies, Z. Bao, O. Travnikova, M. N. Piancastelli

Forskningsoutput: TidskriftsbidragArtikel i vetenskaplig tidskriftPeer review

4 Citeringar (SciVal)

Sammanfattning

The bonding configuration and electronic structure of ethylene oxide adsorbed on Si(100)-(2 x 1) is investigated with fully polarization resolved X-ray absorption spectroscopy as well as with core level and valence band photoemission spectroscopy. Ethylene oxide is found to adsorb via a ring-opening reaction, where the molecule forms a five-membered ring together with the silicon surface dimer atoms inserting between a carbon and the oxygen atom. In the resulting geometry, the molecule is tilted out of the surface plane.
Originalspråkengelska
Sidor (från-till)16077-16082
TidskriftJournal of Physical Chemistry C
Volym113
Utgåva36
DOI
StatusPublished - 2009

Ämnesklassifikation (UKÄ)

  • Fysik
  • Naturvetenskap

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