Synthesis, characterisation and crystal structure of a novel nickel(II) phosphine complex, trans-[Ni2Cl4{cis-(Cy2PCH2)(2)C6H4}(2)]

Magnus Johnson; Ola Wendt

doi:10.1016/j.ica.2010.12.007

Synthesis, characterisation and crystal structure of a novel nickel(II) phosphine complex, trans-[Ni2Cl4{cis-(Cy2PCH2)(2)C6H4}(2)]

Magnus Johnson, Ola Wendt

Centrum för analys och syntes

Forskningsoutput: Tidskriftsbidrag › Artikel i vetenskaplig tidskrift › Peer review

Sammanfattning

The reaction of 1,3-C6H4(CH2PCy2)(2) with anhydrous nickel(II) chloride in dry THF produces the non-cyclometallated dinuclear complex trans-[Ni2Cl4{cis-(Cy2PCH2)(2)C6H4}(2)]. The compound was characterised by H-1, P-31 and C-13 NMR spectroscopy and its solid state structure was determined by X-ray diffraction. An improved synthetic procedure of the aromatic pincer ligand 1,3-C6H4(CH2PCy2)(2) is reported. (C) 2011 Elsevier B.V. All rights reserved.

Originalspråk	engelska
Sidor (från-till)	222-224
Tidskrift	Inorganica Chimica Acta
Volym	367
Nummer	1
DOI	https://doi.org/10.1016/j.ica.2010.12.007
Status	Published - 2011

Bibliografisk information

The information about affiliations in this record was updated in December 2015.
The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)

Ämnesklassifikation (UKÄ)

Organisk kemi

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10.1016/j.ica.2010.12.007

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title = "Synthesis, characterisation and crystal structure of a novel nickel(II) phosphine complex, trans-[Ni2Cl4{cis-(Cy2PCH2)(2)C6H4}(2)]",

abstract = "The reaction of 1,3-C6H4(CH2PCy2)(2) with anhydrous nickel(II) chloride in dry THF produces the non-cyclometallated dinuclear complex trans-[Ni2Cl4{cis-(Cy2PCH2)(2)C6H4}(2)]. The compound was characterised by H-1, P-31 and C-13 NMR spectroscopy and its solid state structure was determined by X-ray diffraction. An improved synthetic procedure of the aromatic pincer ligand 1,3-C6H4(CH2PCy2)(2) is reported. (C) 2011 Elsevier B.V. All rights reserved.",

keywords = "Nickel, Phosphine, Cyclometallation, Pincer ligands",

author = "Magnus Johnson and Ola Wendt",

note = "The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)",

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doi = "10.1016/j.ica.2010.12.007",

language = "English",

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T1 - Synthesis, characterisation and crystal structure of a novel nickel(II) phosphine complex, trans-[Ni2Cl4{cis-(Cy2PCH2)(2)C6H4}(2)]

AU - Johnson, Magnus

AU - Wendt, Ola

N1 - The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)

PY - 2011

Y1 - 2011

N2 - The reaction of 1,3-C6H4(CH2PCy2)(2) with anhydrous nickel(II) chloride in dry THF produces the non-cyclometallated dinuclear complex trans-[Ni2Cl4{cis-(Cy2PCH2)(2)C6H4}(2)]. The compound was characterised by H-1, P-31 and C-13 NMR spectroscopy and its solid state structure was determined by X-ray diffraction. An improved synthetic procedure of the aromatic pincer ligand 1,3-C6H4(CH2PCy2)(2) is reported. (C) 2011 Elsevier B.V. All rights reserved.

AB - The reaction of 1,3-C6H4(CH2PCy2)(2) with anhydrous nickel(II) chloride in dry THF produces the non-cyclometallated dinuclear complex trans-[Ni2Cl4{cis-(Cy2PCH2)(2)C6H4}(2)]. The compound was characterised by H-1, P-31 and C-13 NMR spectroscopy and its solid state structure was determined by X-ray diffraction. An improved synthetic procedure of the aromatic pincer ligand 1,3-C6H4(CH2PCy2)(2) is reported. (C) 2011 Elsevier B.V. All rights reserved.

KW - Nickel

KW - Phosphine

KW - Cyclometallation

KW - Pincer ligands

U2 - 10.1016/j.ica.2010.12.007

DO - 10.1016/j.ica.2010.12.007

M3 - Article

SN - 0020-1693

VL - 367

SP - 222

EP - 224

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 1

ER -

Synthesis, characterisation and crystal structure of a novel nickel(II) phosphine complex, trans-[Ni2Cl4{cis-(Cy2PCH2)(2)C6H4}(2)]

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