Synthesis of a platinum(II) bis(trimethylsilyl)amido complex: A better starting material for the cyclometalation of pincer ligands

Athimoolam Arunachalampillai; Magnus Johnson; Ola Wendt

doi:10.1021/om800444g

Synthesis of a platinum(II) bis(trimethylsilyl)amido complex: A better starting material for the cyclometalation of pincer ligands

Athimoolam Arunachalampillai, Magnus Johnson, Ola Wendt

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Sammanfattning

Treatment of [(COD)PtCl2] with LiN(SiMe3)(2) gives [COD]PtClN(SiMe3)(2) in high yield. This product was fully characterized, including an X-ray structure. From a number of examples it is shown to be a very convenient starting material for the preparation of PXP platinum pincer complexes, giving excellent yields of the cyclometalated product under mild conditions.

Originalspråk	engelska
Sidor (från-till)	4541-4543
Tidskrift	Organometallics
Volym	27
Nummer	17
DOI	https://doi.org/10.1021/om800444g
Status	Published - 2008

Bibliografisk information

The information about affiliations in this record was updated in December 2015.
The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)

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10.1021/om800444g

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title = "Synthesis of a platinum(II) bis(trimethylsilyl)amido complex: A better starting material for the cyclometalation of pincer ligands",

abstract = "Treatment of [(COD)PtCl2] with LiN(SiMe3)(2) gives [COD]PtClN(SiMe3)(2) in high yield. This product was fully characterized, including an X-ray structure. From a number of examples it is shown to be a very convenient starting material for the preparation of PXP platinum pincer complexes, giving excellent yields of the cyclometalated product under mild conditions.",

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AU - Arunachalampillai, Athimoolam

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AU - Wendt, Ola

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PY - 2008

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AB - Treatment of [(COD)PtCl2] with LiN(SiMe3)(2) gives [COD]PtClN(SiMe3)(2) in high yield. This product was fully characterized, including an X-ray structure. From a number of examples it is shown to be a very convenient starting material for the preparation of PXP platinum pincer complexes, giving excellent yields of the cyclometalated product under mild conditions.

U2 - 10.1021/om800444g

DO - 10.1021/om800444g

M3 - Article

SN - 1520-6041

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Synthesis of a platinum(II) bis(trimethylsilyl)amido complex: A better starting material for the cyclometalation of pincer ligands

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