The vibrational spectrum of H2O3.

Anders Engdahl; Bengt Nelander

doi:10.1126/science.1067235

The vibrational spectrum of H2O3.

Anders Engdahl, Bengt Nelander

Forskningsoutput: Tidskriftsbidrag › Artikel i vetenskaplig tidskrift › Peer review

Sammanfattning

This report presents positive infrared spectroscopic identification of H2O3, a higher oxide of hydrogen of importance for the understanding of the chain formation ability of atomic oxygen and a possible intermediate in hydrogen oxygen radical chemistry. All fundamental vibrations of H2O3, isolated in an argon matrix, have been observed. In addition, several bands of HDO3, D2O3, and H2(16)O2(18)O have been measured. One particular mode, the antisymetric O-O stretch at 776 cm-1, should be observable even in the presence of high water concentrations.

Originalspråk	engelska
Sidor (från-till)	482-483
Tidskrift	Science
Volym	295
Nummer	5554
DOI	https://doi.org/10.1126/science.1067235
Status	Published - 2002

Bibliografisk information

The information about affiliations in this record was updated in December 2015.
The record was previously connected to the following departments: Chemical Physics (S) (011001060), Max-laboratory (011012005)

Ämnesklassifikation (UKÄ)

Atom- och molekylfysik och optik (Här ingår: Kemisk fysik, kvantoptik)

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title = "The vibrational spectrum of H2O3.",

abstract = "This report presents positive infrared spectroscopic identification of H2O3, a higher oxide of hydrogen of importance for the understanding of the chain formation ability of atomic oxygen and a possible intermediate in hydrogen oxygen radical chemistry. All fundamental vibrations of H2O3, isolated in an argon matrix, have been observed. In addition, several bands of HDO3, D2O3, and H2(16)O2(18)O have been measured. One particular mode, the antisymetric O-O stretch at 776 cm-1, should be observable even in the presence of high water concentrations.",

author = "Anders Engdahl and Bengt Nelander",

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AU - Nelander, Bengt

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N2 - This report presents positive infrared spectroscopic identification of H2O3, a higher oxide of hydrogen of importance for the understanding of the chain formation ability of atomic oxygen and a possible intermediate in hydrogen oxygen radical chemistry. All fundamental vibrations of H2O3, isolated in an argon matrix, have been observed. In addition, several bands of HDO3, D2O3, and H2(16)O2(18)O have been measured. One particular mode, the antisymetric O-O stretch at 776 cm-1, should be observable even in the presence of high water concentrations.

AB - This report presents positive infrared spectroscopic identification of H2O3, a higher oxide of hydrogen of importance for the understanding of the chain formation ability of atomic oxygen and a possible intermediate in hydrogen oxygen radical chemistry. All fundamental vibrations of H2O3, isolated in an argon matrix, have been observed. In addition, several bands of HDO3, D2O3, and H2(16)O2(18)O have been measured. One particular mode, the antisymetric O-O stretch at 776 cm-1, should be observable even in the presence of high water concentrations.

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JO - Science

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ER -

The vibrational spectrum of H2O3.

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