The water-hydroxyl radical complex: A matrix isolation study.

Anders Engdahl; Gunnar Karlström; Bengt Nelander

doi:10.1063/1.1563608

The water-hydroxyl radical complex: A matrix isolation study.

Anders Engdahl, Gunnar Karlström, Bengt Nelander

Forskningsoutput: Tidskriftsbidrag › Artikel i vetenskaplig tidskrift › Peer review

Sammanfattning

The water–hydroxyl radical complex was prepared by irradiating peroxy radicals in hydrogen-doped argon matrices. The low water content of the matrices made it possible to observe the fundamental bands of the complexed water molecule. The experimental results are compared with the results from ab initio calculations. The complex rotates around the O–O axis in the matrix. ©2003 American Institute of Physics.

Originalspråk	engelska
Sidor (från-till)	7797-7802
Tidskrift	Journal of Chemical Physics
Volym	118
Nummer	17
DOI	https://doi.org/10.1063/1.1563608
Status	Published - 2003

Bibliografisk information

The information about affiliations in this record was updated in December 2015.
The record was previously connected to the following departments: Chemical Physics (S) (011001060), Theoretical Chemistry (S) (011001039), Max-laboratory (011012005)

Ämnesklassifikation (UKÄ)

Atom- och molekylfysik och optik (Här ingår: Kemisk fysik, kvantoptik)
Teoretisk kemi (Här ingår: Beräkningskemi)

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abstract = "The water–hydroxyl radical complex was prepared by irradiating peroxy radicals in hydrogen-doped argon matrices. The low water content of the matrices made it possible to observe the fundamental bands of the complexed water molecule. The experimental results are compared with the results from ab initio calculations. The complex rotates around the O–O axis in the matrix. {\textcopyright}2003 American Institute of Physics.",

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AB - The water–hydroxyl radical complex was prepared by irradiating peroxy radicals in hydrogen-doped argon matrices. The low water content of the matrices made it possible to observe the fundamental bands of the complexed water molecule. The experimental results are compared with the results from ab initio calculations. The complex rotates around the O–O axis in the matrix. ©2003 American Institute of Physics.

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The water-hydroxyl radical complex: A matrix isolation study.

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