Towards longer-lived metal-to-ligand charge transfer states of iron(ii) complexes: an N-heterocyclic carbene approach.

Yizhu Liu, Tobias Harlang, Sophie Canton, Pavel Chabera, Karina Suarez Alcantara, André Fleckhaus, Dimali Vithanage, Erik Göransson, Alice Corani, Reiner Lomoth, Villy Sundström, Kenneth Wärnmark

Forskningsoutput: TidskriftsbidragArtikel i vetenskaplig tidskriftPeer review

172 Citeringar (SciVal)

Sammanfattning

A 9 ps (3)MLCT lifetime was achieved by a Fe(II) complex based on C(NHC)⁁N(py)⁁C(NHC) pincer ligands. This is the longest known so far for any kind of complexes of this abundant metal, and increased by almost two orders of magnitude compared to the reference Fe(II) bis-terpyridine complex.
Originalspråkengelska
Sidor (från-till)6412-6414
TidskriftChemical Communications
Volym49
Utgåva57
DOI
StatusPublished - 2013

Bibliografisk information

The information about affiliations in this record was updated in December 2015.
The record was previously connected to the following departments: Centre for Analysis and Synthesis (011001266), Max-laboratory (011012005), Chemical Physics (S) (011001060)

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