TY - JOUR
T1 - Understanding the Fate of H2S Injected in Basalts by Means of Time-Domain Induced Polarization Geophysical Logging
AU - Lévy, L.
AU - Ciraula, Daniel
AU - Legros, Bruno
AU - Martin, T.
AU - Weller, A.
N1 - Publisher Copyright:
© 2024. The Author(s).
PY - 2024/6
Y1 - 2024/6
N2 - To help meet emission standards, hydrogen sulfide (H2S) from geothermal production may be injected back into the subsurface, where basalt offers, in theory, the capacity to mineralize H2S into pyrite. Ensuring the viability of this pollution mitigation technology requires information on how much H2S is mineralized, at what rate and where. To date, monitoring efforts of field-scale H2S reinjection have mostly occurred via mass balance calculations, typically capturing less than 5% of the injected fluid. While these studies, along with laboratory experiments and geochemical models, conclude effective H2S mineralization, their extrapolation to quantify mineralization and its persistence over time leads to considerable uncertainty. Here, a geophysical methodology, using time-domain induced polarization (TDIP) logging in two of the injection wells (NN3 and NN4), is developed as a complementary tool to follow the fate of H2S re-injected at Nesjavellir geothermal site (Iceland). Results show a strong chargeability increase at +40 days, interpreted as precipitation of up to 2 vol.% based on laboratory relationships. A uniform increase is observed along NN4, whereas it is localized below 450 m in NN3. Changes are more pronounced with larger electrode spacing, indicating that pyrite precipitation takes place away from the wells. Furthermore, a chargeability decrease is observed at later monitoring rounds in both wells, suggesting that pyrite is either passivated or re-dissolved after precipitating. These results highlight that a sequence of overlapping reactive processes (pyrite precipitation, passivation, pore clogging and possibly pyrite re-dissolution) results from H2S injection and that TDIP monitoring is sensitive to this sequence.
AB - To help meet emission standards, hydrogen sulfide (H2S) from geothermal production may be injected back into the subsurface, where basalt offers, in theory, the capacity to mineralize H2S into pyrite. Ensuring the viability of this pollution mitigation technology requires information on how much H2S is mineralized, at what rate and where. To date, monitoring efforts of field-scale H2S reinjection have mostly occurred via mass balance calculations, typically capturing less than 5% of the injected fluid. While these studies, along with laboratory experiments and geochemical models, conclude effective H2S mineralization, their extrapolation to quantify mineralization and its persistence over time leads to considerable uncertainty. Here, a geophysical methodology, using time-domain induced polarization (TDIP) logging in two of the injection wells (NN3 and NN4), is developed as a complementary tool to follow the fate of H2S re-injected at Nesjavellir geothermal site (Iceland). Results show a strong chargeability increase at +40 days, interpreted as precipitation of up to 2 vol.% based on laboratory relationships. A uniform increase is observed along NN4, whereas it is localized below 450 m in NN3. Changes are more pronounced with larger electrode spacing, indicating that pyrite precipitation takes place away from the wells. Furthermore, a chargeability decrease is observed at later monitoring rounds in both wells, suggesting that pyrite is either passivated or re-dissolved after precipitating. These results highlight that a sequence of overlapping reactive processes (pyrite precipitation, passivation, pore clogging and possibly pyrite re-dissolution) results from H2S injection and that TDIP monitoring is sensitive to this sequence.
KW - borehole logging
KW - gas storage
KW - geothermal
KW - H2S
KW - pyrite
KW - time-domain induced polarization
UR - http://www.scopus.com/inward/record.url?scp=85195269582&partnerID=8YFLogxK
U2 - 10.1029/2023JB028316
DO - 10.1029/2023JB028316
M3 - Article
AN - SCOPUS:85195269582
SN - 2169-9313
VL - 129
JO - Journal of Geophysical Research: Solid Earth
JF - Journal of Geophysical Research: Solid Earth
IS - 6
M1 - e2023JB028316
ER -